ngµç×ÓÓÎÏ·

05

¿ÆÑÐÏ£Íû

»¯Ñ§Ñ§Ôº³ØÕñ¹ú½ÌÊÚÑо¿ÍŶÓ£º£ºÁ¦Ö·¢¹âÖÊÁÏϵͳµÄÐÂÉè¼ÆÕ½ÂÔ

¸å¼þȪԴ£º£º»¯Ñ§Ñ§Ôº | ×÷Õߣº£º»¯Ñ§Ñ§Ôº ÔĶÁÁ¿£º£º

Á¦Ö·¢¹â£¨Mechanoluminescence, ML£©£¬£¬ÓÖ³ÆĦ²Á·¢¹â¡¢¡¢¶ÏÁÑ·¢¹â»òѹµç·¢¹â£¬£¬ÊÇÖ¸¹ÌÌåÖÊÁÏÔÚ»úеÍâÁ¦×÷ÓÃÏÂÆÆËé»òÐαä¶ø±¬·¢·¢¹â£¬£¬ÕâÊÇÖ±½Ó½«»úеÄÜתÄð³É¹âÄܵÄÒ»ÖÖ·¢¹âÕ÷Ï󡣡£¡£¡£¡£ÓëÆäËüÀàÐ͵ķ¢¹âÏà±È£¬£¬Á¦Ö·¢¹â²»ÐèÒªÍâ¼Óµçѹ»ò×ÏÍâ¹âÕÕÉäµÈ¼¤ÆðÔ´£¬£¬ÆäÇéÐÎÓѺõÄÒý·¢·½Ê½Ê¹µÃÁ¦Ö·¢¹âÖÊÁÏÔÚÓ¦Á¦´«¸Ð¡¢¡¢Ñ¹¹âÕÕÃ÷ºÍ¼ÓÃÜ·ÀαµÈÁìÓò¾ßÓÐÖ÷ÒªµÄDZÔÚÓ¦Óᣡ£¡£¡£¡£2010Äê×îÏÈ£¬£¬ngµç×ÓÓÎÏ·»¯Ñ§Ñ§Ôº³ØÕñ¹ú½ÌÊÚÑо¿ÍŶÓÔÚȺ¼¯ÓÕµ¼·¢¹â£¨AIE£©ÖÊÁϵÄÁ¦Ö·¢¹â±äÉ«·½Ãæ×öÁË´ó×Ú̽Ë÷ÐÔµÄÑо¿ÊÂÇ飬£¬·¢Ã÷ÁËÁ¦Ö·¢¹â±äÉ«ÊǾø´ó´ó¶¼AIEÖÊÁϵÄÒ»¸ö¹²ÐÔ¡£¡£¡£¡£¡£¸Ã¹²ÐԵķ¢Ã÷£¬£¬¾ßÓÐÖ÷ÒªµÄѧÊõÒâÒ壬£¬Îª½â¾öÁ¦Ö·¢¹â±äÉ«ÖÊÁÏÏ£º±ÎÊÌâ¼°Ôö½ø¸ÃÀàÖÇÄÜÖÊÁϵÄÓ¦ÓÃÑо¿ÌṩÁËÒ»¸öÇÐʵ¿ÉÐеĽâ¾ö·½°¸¡£¡£¡£¡£¡£

ÔÚÉÏÊöÑо¿»ù´¡ÉÏ£¬£¬2015Ä꣬£¬¸ÃÑо¿ÍŶÓÓÖÊ״η¢Ã÷ÁËȺ¼¯ÓÕµ¼Èȼ¤»îÑÓ³ÙÓ«¹â£¨AIE-TADF£©ÖÊÁϾßÓÐÁ¦Ö·¢¹âÕ÷Ïó£¨Angew. Chem. Int. Ed., 2015, 54, 874-878£©£¬£¬È»ºóÓÖ·¢Ã÷ÁËһЩAIE·Ö×Ó¾ßÓÐÁ¦Ö·¢¹âÐÔÄÜ£¬£¬²¢¶ÔÆ䱬·¢ÆøÀí¾ÙÐÐÁËÉîÈëÑо¿£¨Chem. Sci., 2015, 6, 3236-3241£»£»Chem. Sci., 2016, 7, 5307-5312£»£»Chem. Sci., 2018, 9, 5787-5794£©¡£¡£¡£¡£¡£2017Ä꣬£¬Î人´óѧÀîÕñ½ÌÊÚÍŶÓÓë³ØÕñ¹ú½ÌÊÚÍŶÓÏàÖú£¬£¬·¢Ã÷ÁËһЩ´¿ÓлúÁ×¹âÖÊÁϾßÓÐÁ¦Ö·¢¹âÕ÷Ï󣬣¬°ÑÁ¦Ö·¢¹âÍØÕ¹µ½ÓлúÁ×¹âÁìÓò£¨Angew. Chem. Int. Ed., 2017, 56, 15299-15303£»£»Angew. Chem. Int. Ed., 2017, 56, 880-884£©¡£¡£¡£¡£¡£2018Ä꣬£¬³ØÕñ¹ú½ÌÊÚÍŶÓÓÖ·¢Ã÷ÁËÁ¦Ö³¤Óà»Ô·¢¹âÕ÷Ïó£¨Chem. Sci., 2018, 9, 3782-3787£©£¬£¬ÖÁ´Ë£¬£¬´¿ÓлúÖÊÁϵÄÁ¦Òý·¢·¢ÉäÓ«¹â¡¢¡¢TADF¡¢¡¢Á×¹â»ò³¤Óà»ÔµÈ²î±ð·¢¹âÀàÐ͵ÄÁ¦Ö·¢¹âƴͼƴÆë¡£¡£¡£¡£¡£2018Ä꣬£¬³ØÕñ¹ú½ÌÊÚÍŶӣ¨Angew. Chem. Int. Ed., 2018, 57, 12727-12732£©ÓëÇൺ¿Æ¼¼´óѧÑîÎľý½ÌÊÚÍŶӣ¨Chem. Commun., 2018, 54, 8206-8209£©Í¬Ê±Ñо¿·¢Ã÷£¬£¬½«Ö÷ÌåÖÊÁÏ£¨¾ßÓÐÁ¦Ö·¢¹âÐÔÄÜ£©Óë²î±ð¿ÍÌå·¢¹âÖÊÁÏ£¨²»¾ßÓÐÁ¦Ö·¢¹âÐÔÄÜ£©¾ÙÐи´ºÏ£¬£¬¿ÉÒÔͨ¹ý»úеÁ¦Òý·¢²î±ð·¢¹âÑÕÉ«¿ÍÌå·Ö×Ó±¬·¢·¢¹â£¬£¬´Ó¶ø°ÑÁ¦Ö·¢¹âÖÊÁÏϵͳ´Ó´¿Óлúµ¥×é·Ö½øÒ»²½ÍØÕ¹µ½¸´ºÏϵͳ£¬£¬¼«´óµØ¸»ºñÁËÓлúÁ¦Ö·¢¹âÖÊÁÏϵͳ¡£¡£¡£¡£¡£

Ê×Ò³|ngµç×ÓÓÎÏ·Öйú¼¯ÍŹٷ½ÍøÕ¾

¿ËÈÕ£¬£¬ngµç×ÓÓÎÏ·»¯Ñ§Ñ§Ôº³ØÕñ¹ú½ÌÊÚÑо¿ÍŶÓÌá³öʹÓÃÒ»ÖÖÔ½·¢¼òÆÓµÄÒªÁìÀ´¾«×¼Éè¼ÆÁ¦Ö·¢»Ö¸´ºÏÖÊÁÏϵͳµÄÐÂÉè¼ÆÕ½ÂÔ¡£¡£¡£¡£¡£¸ÃÕ½ÂÔÉè¼ÆµÄÁ¦Ö·¢»Ö¸´ºÏÖÊÁÏϵͳÖУ¬£¬µ¥¶ÀµÄÖ÷ÌåÖÊÁϺͿÍÌåÖÊÁ϶¼²»¾ßÓÐÁ¦Ö·¢¹âÐÔÄÜ£¬£¬¿ÉÊÇͨ¹ýÖ÷¿ÍÌ帴ºÏ»ñµÃµÄ¸´ºÏϵͳÔò¾ßÓÐÁ¦Ö·¢¹âÐÔÄÜ£¬£¬ÊµÏÖÁË´ÓÎÞµ½ÓеÄÁ¦Ö·¢¹â¡£¡£¡£¡£¡£Í¬Ê±£¬£¬¿ÍÌåÖÊÁϵÄÑ¡Ôñ¹æÄ£ºÜÊǹ㣬£¬¿ÉÒÔÊÇ´¿Óлú·¢¹âÖÊÁÏ¡¢¡¢ÅäºÏÎïÁ×¹âÖÊÁÏ£¬£¬Ò²¿ÉÒÔÊÇÎÞ»úÁ¿×ӵ㷢¹âÖÊÁϵȵȡ£¡£¡£¡£¡£Í¨¹ý¸Ä±ä¿ÍÌåÖÊÁϵÄÖÖÀ࣬£¬ºÜÊÇÈÝÒ×µ÷ÀíÁ¦Ö·¢¹âµÄ·¢¹âÑÕÉ«¡¢¡¢ÁÁ¶È¡¢¡¢É«´¿¶ÈÒÔ¼°·¢¹âÊÙÃüµÈÐÔÄÜ£¬£¬¼«´óµØ¸»ºñÁËÁ¦Ö·¢¹âÖÊÁϵÄÑо¿ÄÚÔÚ¡£¡£¡£¡£¡£Á¬Ïµ¹âÎïÀí²âÊÔºÍÀíÂÛÅÌË㣬£¬ÉîÈë̽ÌÖÕâÀàÐÂÐÍÁ¦Ö·¢»Ö¸´ºÏϵͳµÄÒý·¢Àú³ÌºÍ·¢ÉäÀú³Ì£¬£¬²¢Õ¹ÏÖÁ˸´ºÏÏÏû³Á¦Ö·¢¹âµÄ¼¤»î»úÖÆÊÇÔ´ÓÚѹµçЧӦºÍÖ÷¿ÍÌå·Ö×ÓµÄÄÜÁ¿×ªÒÆ¡£¡£¡£¡£¡£

ÉÏÊöÑо¿Ð§¹û½ÒÏþÓÚAngewandte Chemie International Edition£¬£¬ngµç×ÓÓÎÏ·»¯Ñ§Ñ§ÔºÎªµÚÒ»Íê³Éµ¥Î»¡£¡£¡£¡£¡££¨Wenlang Li, Qiuyi Huang, Zhan Yang, Xiaoyue Zhang, Dongyu Ma, Juan Zhao, Chao Xu, Zhu Mao, Yi Zhang, Zhenguo Chi. Activating versatile mechanoluminescence in organic host©\guest crystals by controlling exciton transfer. Angew. Chem. Int. Ed., 2020, DOI: 10.1002/anie.202010166£©¡£¡£¡£¡£¡£

ÂÛÎÄÁ´½Ó£º£ºhttps://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202010166

¡¾ÍøÕ¾µØͼ¡¿